![]() Temperature Monitoring Unit
专利摘要:
The invention relates to a temperature control unit comprising an elongated thermo-bimorph temperature bending element (1) which is bendable in a given bending direction (X) and a temperature change from a starting position and an exit temperature in a predetermined bending direction (X) and opposite temperature change in the same bending plane in a reverse bending direction (-X) Temperature monitoring unit comprises an indicator element (3) for detecting an impermissible change in temperature, the temperature bending element (1) has a first latching element (21) at its free end, and a second latching element (22) is provided, the first latching element (21) following a first latching element (21) bending of the temperature bending element (1) in the bending direction (X) with the second latching element (22) is interacting, wherein between the first latching element (21) and the second latching element (22) in the direction (X) a relative displacement is possible and in the bending direction (- X ) causes a movement blocking, whereby the second latching element (22) from the first latching element (21) in the bending direction (-X) entrainable and with the indicator element (3) in operative contact can be brought. 公开号:AT513653A1 申请号:T50551/2012 申请日:2012-11-30 公开日:2014-06-15 发明作者:Gernot Dipl Ing Schmid;Manfred Dipl Ing Bammer 申请人:Seibersdorf Labor Gmbh; IPC主号:
专利说明:
1 Temperaturüberwachunaseinheit The invention relates to a temperature monitoring unit, according to the preamble of patent claim 1. Temperature monitoring units according to the invention are used in particular for monitoring biological material. Biological materials are stored in vials, ampoules or carpules, which are small glass and plastic containers, in liquid nitrogen, for example at -196 ° C. Several vials are usually housed in a holder, which is stored as a whole in liquid nitrogen. In the case of improper, too slow removal of individual vials, it may occur that the entire holder, including all vials housed in it, is taken out too long from the liquid nitrogen, so that in the meantime, a heating of the vials and the biological material is damaged. Since improper handling can never be ruled out in practice, this means that there is a certain degree of uncertainty as to whether, for a required vial taken from the liquid nitrogen, the cold chain from initial freezing to use, ie final removal, is in fact completely closed was. An interruption of the cold chain would be present, for example, when the vials are at a temperature that endangers the biological material, e.g. -100 ° C are heated, without removing the biological Mäerial and use for the intended purpose directly. Only if it is ensured that the temperature of the vials was consistently below a threshold temperature to be specified, can a biological condition of the material sample be assumed. In order to ensure the complete monitoring of the cold chain of each individual vial, therefore, a cost-effective sensor is desirable, with the one-time and short-term interruption of the cold chain can be reliably detected. Such a sensor has hitherto not been known in the prior art. The object of the invention is therefore to produce a sensor which overcomes this disadvantage. The invention solves this problem with a temperature monitoring unit of the type mentioned above with the characterizing features of claim 1. 2/22 2nd This is achieved with a temperature monitoring unit of the type mentioned with an elongated thermobimorph temperature bending element in that the temperature monitoring unit comprises an indicator element for detecting or indicating an impermissible temperature change, that the temperature bending element has a first latching element at its free end, and that a second Catching element is provided, wherein the first latching element can be brought to a bending direction in bending direction of the temperature bending element with the second latching element in interaction, wherein between the first latching element and the second latching element in the bending direction, a relative displacement is possible and in the bending direction, a movement blocking is effected, whereby the second catch element of the first locking element in the bending direction entrained and engageable with the indicator element in operative contact. The invention solves the problem with a temperature monitoring unit of the type mentioned above with the characterizing features of claim 2. It is provided that the temperature bending element has at one of its ends a first latching element of a latching mechanism that the temperature monitoring unit has an indicator element located in an initial state, the in another state, that the temperature bending element, the latching mechanism, the latching element and the indicator element of the temperature monitoring unit are arranged to each other such that the first latching element of the latching mechanism so far shifts when changing temperature in the bending direction relative to a second latching element of the Council mechanism that the first detent element and the second detent element miteinender cause a blockage of the relative movement of the first detent element relative to the second detent element against the bending direction, and that at subsequently ßender change in temperature in the direction of the initial temperature and the resulting recovery of the temperature bending element, as well as associated with this locking mechanism, the second locking element, the indicator element, preferably irreversibly transferred from the initial state to the second state. Further advantageous embodiments of the temperature monitoring unit are described in the features of the dependent claims. The failure of cooling or heating chains can be easily detected if the indicator element is an electrically conductive rod, wherein the indicator element 3/22 3 in particular consists of graphite and / or in particular is electrically conductively connected at its ends with one electrical contact. A simple structure is achieved in that the indicator element is designed as a glass fiber rod and the second locking element has on its side facing the glass fiber rod side an element for breaking or cutting through the indicator element. The electrical connection between the contacts can be interrupted particularly easily by the second locking element, upon return of the temperature bending element, bending the rod and thereby breaks the electrical connection between the two contacts and in particular breaks the rod. A particularly easy detection of the failure of the cooling or heating chain is achieved when the indicator element is conductively connected via the contacts to electrical components and / or measuring devices, in particular a conductivity meter. A temperature control unit that is easy to implement mechanically is achieved when the first latching element of the latching mechanism displaces so far when cooled in the cooling bending direction of the temperature-bending element relative to a second latching element of the latching mechanism that the first latching element and the second latching element mutually block the relative movement of the first latching element Locking element relative to the second latching element against the Abkühlbiegerichtung cause and that upon subsequent heating and the resulting recovery of the temperature bending element, as well as associated with this locking mechanism, the second locking element, the indicator element from the initial state in the second state, in particular the second locking element, the indicator element bending claimed and the indicator element preferably breaks. A special development of a temperature monitoring unit, which does not need to be removed from the cooling medium during the examination of the cold chain, provides that an RFID / NFC transponder is electrically connected to the contacts and, on request, the presence of the interruption of the electrically conductive connection between the Check contacts and gives a related electromagnetic signal. 4/22 4 This makes handling easier and avoids the danger of destroying the vials themselves during the test. A design of the temperature monitoring unit without any electrical or electronic components is achieved by the indicator element is visible from the outside through a viewing window, wherein the second locking element, upon return of the temperature bending element, on the indicator element generates a recognizable by the viewing window change of the indicator element. The interruption of cooling and heating chains can be achieved particularly easily by visual inspection if the indicator element is visible through a viewing window, wherein the indicator element is designed as a container containing fluid, and in that the second catch element opens the container when the temperature bending element is returned, so that the substance escapes and is visible in the viewing window, the substance producing a color reaction, in particular with a substance applied to a viewing window. A particular aspect of the invention provides that the temperature bending element is connected at its end remote from the first latching element with the indicator element, wherein the indicator element is arranged offset in the bending plane of the temperature bending element and against the temperature bending element against the bending direction. As a result, a particularly space-saving and bracket-free design of the temperature is achieved. In order to protect the temperature monitoring unit from damage, it is advantageous if the locking element remote end of the temperature bending element and the indicator element are rigidly secured to a holder or to each other with a bracket. An easy to realize and cost-effective further development of the invention provides that the first locking element is designed as a locking sleeve with internal tilting in bending direction latching hook, wherein the first locking element has a recess through which the second locking element protrudes, wherein the second locking element at least one tooth , in particular a plurality of teeth arranged one behind the other, and is preferably designed as a toothed rack. 5/22 5 A simple and cost-effective implementation of the thermobimorph temperature bending element provides that the temperature bending element is designed as a bimetal, namely as a metal element with two layers of different metals, which are connected to each other cohesively or positively. In order to detect the failure of the cold chain only after reaching the storage temperature, it can be provided that the arrangement of the locking elements, the relative movement of the first locking element relative to the second locking element against the Abkühlbiegerichtung with a cooling of the temperature bending element in a temperature range from -200 ° C to -50 ° C blotted. However, since temperature fluctuations in storage containers are not harmful, it is advantageous if certain fluctuations are tolerated. For this purpose, it can be provided that after previous cooling when exceeding a threshold temperature, in particular less than or equal to -100 ° C, the consequent regression of the bending of the temperature bending element and the associated locking mechanism, the second locking element, the indicator element from the initial state irreversibly in the second state transferred. In order to monitor individual vials, it is possible to attach the temperature monitoring unit to the wall of a vial. A preferred embodiment of the invention will be explained below with reference to FIGS. 1 to 6. It show schematically 1 a temperature monitoring unit in the starting position, 2 a temperature monitoring unit during cooling, 3 shows a temperature monitoring unit when a threshold temperature is exceeded and the fracture of the indicator element resulting therefrom, 4 is a front view of the locking mechanism of a temperature monitoring unit in the starting position, 5 is a plan view of a locking mechanism of a temperature monitoring unit in the starting position and Fig. 6 shows a possible course of the temperature and the electrical conductance of a temperature monitoring unit. 6/22 6 In the following description of the invention with reference to an embodiment reference numerals designate the same or similar components. 1 to 3 each show a front view of a temperature monitoring unit 10 according to the invention, with an upwardly open trough-shaped holder 7 with bottom 8, for monitoring vials. Vials are small plastic containers used to store and transport biological material. For example, vials are stored in liquid nitrogen at -195 ° C. Preferably, the temperature monitoring unit 10 is stored together with the vials. The temperature monitoring unit 10 has the task of re-heating over a threshold temperature TSchweii (Fig. 6) to detect. On the holder 7 of the temperature monitor 10 is a portion or end portion of the bimetallic strip 1, consisting of two layers of different metals, which are materially or positively connected to each other rigidly attached. Upon cooling, from the starting temperature TAuSgang, (FIG. 6) of the bimetallic strip 1, due to the different dimensions and due to the different expansion coefficients of the metals, a deformation of the bimetallic strip 1 occurs (FIG. 2). A cooling causes in the illustrated Embodiment, a bending of the bimetallic strip 1 in the direction of the bottom 8 of Holder 7. The direction in which the bending metal strip 1 moves on cooling is referred to in the further embodiments as Abkühlbiegerichtung X (Fig. 2) of the bimetallic strip 1. In Fig. 1, the temperature monitoring unit 10 is shown in its initial position before cooling. The bimetallic strip 1 is straight and unbent. At the end of the bimetallic strip 1 is a first latching element 21, which in the present Embodiment of the invention is designed as a latching sleeve 21, connected to the bimetallic strip 1. The locking sleeve 21 consists of a cuboid hollow body 24 with a continuous recess 23 and an internal, tiltable latching hook 5 (Fig. 4, Fig. 5). In the recess 23 of the hollow body 24 is a second locking element 22, which has a partially recessed, the recess 23 passing through rack 22, with successive, sawtooth-shaped teeth 6. The holder 7 is penetrated by a graphite rod 3. The graphite rod 3 is arranged parallel to the bimetallic strip 1 in the bending plane of the bimetallic strip 1, opposite to its cooling bending direction X, and rigidly secured to the holder 7 (FIG. 1). At the 7/22 7 Ends of the graphite rod 3 are electrical contacts 4 a, 4 b placed permanently or as needed for testing conductively connected to an ohmmeter 9 or can be connected. The ohmmeter 9 detects the resistance or conductance G between the contacts 4a and 4b, and thus determines whether the electrical conduction between the contacts 4a and 4b is intact. As shown in Fig. 2, the bimetallic strip 1 bends on cooling, during a cooling time tAbkühiung (Fig. 6), in Abkühlbiegerichtung X. As a result, attached to the bimetallic strip 1 and coupled to the movement detent sleeve 21 lowers in the direction of the bottom 8 , The support of the rack 22 at the bottom 8 of the holder 7, in Abkühlbiegerichtung X causes lowering of the locking sleeve 21, a relative movement of the locking sleeve 21 relative to the rack 22. Since the latching hook 5 is tiltably mounted, the jamming of the locking sleeve 21 and the rack 22, prevented in the movement of the locking sleeve 21 in Abkühlbiegerichtung X relative to the rack 22. During the lowering of the latching sleeve 21 in Abkühlbiegerichtung X of the latching hook 5 slides along the edges of the sawtooth teeth 6 of the rack 22 along and is thereby tilted (Fig. 2). The flanks of the latching hook 5 and the teeth 6 are, as shown in Fig. 4, in this embodiment counter-shaped and adapted to each other. This concrete design of the latching hook 5 and the teeth 6 causes at a dipping of the latching hook 5 in the tooth gaps of the rack 22, after cooling from the initial position by a cooling temperature ATAbküh | Ung (Fig. 6), latching at a latching temperature TRas, and a blocking of the relative movement of the locking sleeve 21 relative to the rack 22, against the Abkühlbiegerichtung X. After cooling, the vials are stored at a constant temperature. This is shown in FIG. 6 with the storage time t storage · The ohmmeter 9 detects the electrical connection between the contacts 4a and 4b during the cooling time tAbkühiung and the storage time t | _ager (Fig. 2, Fig. 6). The graphite rod 3 remains conductive throughout the process. In an alternative embodiment of the invention, the ohmmeter 9 can also be connected to the contacts 4a and 4b only for the purpose of subsequently checking whether the cold chain has remained intact and does not need to be supplied to the temperature monitoring unit 10 during the entire process or parts of the cooling or heating process be connected. Fig. 3 shows the case of an interruption of the cold chain, wherein after cooling time tAbkühiUng the temperature monitoring unit 10 below the locking temperature 8/22 8 TRast (Fig. 6) takes place subsequent heating by a fracture temperature ÄTBruchj. Warming above a threshold temperature T wedge (FIG. 6) would damage the vials and the biological material therein and is therefore detected by the temperature monitoring unit 10. When heating the temperature monitoring unit 10 and the bimetallic strip 1 therein by the fracture temperature ATBruch, the bimetallic strip 1, as shown in Fig. 3, moves against the Abkühlbiegerichtung X in the direction of the initial position. By engaging in the latching temperature TRasl latching of the latching hook 5 with the rack 22 (FIG. 4), the movement coupling of the latching sleeve 21 with the bimetallic strip 1 and the rack 22 is displaced by the latching sleeve 21 against the Abkühlbiegerichtung X. By entraining the rack 22 of the graphite rod 3 is subjected to bending of this and bent against the Abkühlbiegerichtung X. When a threshold temperature T wweiwei (FIG. 6) of, for example: -100 ° C. is exceeded, the existing bending stress applied by the toothed rack 22 to the graphite rod 3 in a critical cross section 25 of the graphite rod 3 exceeds the maximum breaking stress. This leads to component failure or breakage of the graphite rod 3. The rod 3 has a positive temperature coefficient in the present embodiment. The course of the conductivity G over the time t is shown in FIG. Since the material has a positive temperature coefficient, the conductivity G increases with decreasing temperature. During the cooling time Wühiung or with decreasing temperature in the rod 3, the electrical conductivity G, during the storage time tLager, the electrical conductivity G then remains constant and then falls when heating the rod 3 in the direction of the output temperature again. In the case of a breakage of the rod 3, the conductivity drops to 0. The rod 3 may alternatively consist of a material with a negative temperature coefficient. The conductivity G decreases with decreasing temperature. During the cooling time t-cooling or when the temperature in the rod 3 drops, the electrical conductivity G drops during the storage time t-bearing, the electrical conductivity G then remains constant and then rises again when the rod 3 heats up in the direction of the starting temperature. From the course shown in FIG. 6, the conductivity G of the rod 3 then has an analogously opposite or reciprocal profile of the conductivity G. The ohmmeter 9 detects the interruption of the electrical connection between the contacts 4a and 4b, which, as shown in Fig. 3 are at the ends of the graphite rod 3 9/22. Upon renewed cooling of the vials and thus of the temperature monitoring unit 10 below the threshold temperature T wedge of, for example: -100 ° C., the ohmmeter 9 further determines the breakage of the graphite rod 3, even if the current temperature is below the threshold temperature T wedge (FIG. 6). As a result, even if the threshold temperature T.sub.Wei is subsequently fallen below again in a subsequent period t.sub.2 (FIG. 6), the one-time exceeding and thus the failure of the cold chain can be displayed. Alternatively, it is possible to transmit the state of the graphite rod 3 via an integrated in the temperature monitoring unit 10 RFID / NFC transponder to an external data communication device. In this case, the RFID / NFC transponder is connected to the electrical contacts 4a and 4b. An electrical circuit integrated in the RFID / NFC transponder detects whether the electrical connection between the contacts 4a and 4b is interrupted. Upon request of an external data communication device, the state of the RFID / NFC transponder is transmitted via an antenna to the data communication device. Instead of the bimetallic strip 1, any thermo-bimorph element may be used, which is arranged and designed such that it changes its position with changing temperature and is pivoted or bent when bent in the bending direction X. Alternatively, any other suitable electrically conductive element may be used instead of the graphite rod 3, this is, for example, a film which is pierced and destroyed during the return of the second latching element 22, so that the electrical conductivity becomes zero. As an additional alternative to the detection of the interruption of cold chains by the interruption of an electric circuit shown in FIGS. 1 to 6, the interruption of an optical waveguide, for example a glass fiber, can take place. In this case, the indicator element 3 is formed by a glass fiber cable. If the temperature is changed again in the direction of the starting temperature, the second locking element 22 breaks or cuts through the glass fiber line. The interruption of the line can be detected by a light source introduces light waves in the fiber optic cable and her arrive at the end of the line is checked by a detector. A further variant of the invention provides for the detection of the interruption of cold chains by visual changes to the temperature monitoring unit 10 to reach 10/22 10. A visual change is z. B. a detectable by a viewing window curvature of the indicator element 3 or as long as the indicator element 3 is intact, an object through the viewing window can be seen. In case of breakage or impairment of the indicator element 3 by the locking element 22, this object is moved or ejected and is therefore no longer visible through the viewing window. If the object is no longer visible, this means that the cooling or heating chain has been interrupted. It is also possible to detect the interruption of cooling or thermal chains by changing the color of certain parts of the temperature monitoring unit 10. The indicator element 3 is designed as a container and contains a substance, e.g. a gas. Upon return of the temperature bending element 1 in the starting position and the attached and latched locking elements 21 and 22, the container is broken by the locking element 22 and the substance exits and discolored the temperature monitoring unit 10 or parts of the temperature monitoring 10. The substance can in particular with an The second substance attached to the viewing window reacts such that the viewing window discolors. As an alternative to detecting the interruption of cold chains, heat chains can also be monitored. In this case, the thermobimorph temperature element 1 is mounted in such a way that the bending direction X shown in FIG. 1 coincides with the bending direction of the temperature element 1 when heated. In the embodiment described in FIGS. 1 to 3, this effect is already achieved when the bimetallic strip 1 is mounted so as to be 180 ° about its longitudinal axis, the two metal layers of the bimetallic strip 1 being interchangeable with the previously shown embodiment. 11/22
权利要求:
Claims (17) [1] 1 temperature monitoring unit comprising an elongated thermobimorph temperature bending element (1) which is bendable in a given direction of bending (X) at a temperature change from a starting position and a starting temperature in opposite bending temperature change in the same bending plane in an opposite bending direction (-X) , characterized in that the temperature monitoring unit comprises an indicator element (3) for detecting or indicating an impermissible temperature change, that the temperature bending element (1) at its free end a first latching element (21), and in that a second latching element (22) is provided in which the first latching element (21) can be brought into interaction with the second latching element (22) after bending of the temperature bending element (1) in the bending direction (X), wherein between the first latching element (21) and the second latching element (22) Bending direction (X) a relative displacement möglic h and in the bending direction (-X) a movement blocking is effected, whereby the second locking element (22) from the first locking element (21) in the bending direction (-X) entrainable and with the indicator element (3) can be brought into operative contact. [2] 2. Temperature monitoring unit, in particular according to claim 1, comprising an elongate thermobimorphic temperature bending element (1), which bends at a change in temperature from a starting position and an initial temperature in a bending plane according to a predetermined bending direction (X), characterized in that the temperature bending element (1 ) has at one of its ends a first latching element (21) of a latching mechanism (2) that the temperature monitoring unit has an indicator element (3) located in an initial state, which can be brought into a further state that the temperature bending element (1), the latching mechanism ( 2), the latching element (21) and the indicator element (3) of the temperature monitoring unit are arranged such that the first latching element (21) of the latching mechanism (2) with temperature change in the bending direction (X) relative to a second latching element (22) of the Council mechanism (2), displaced so far that the first locking element ( 21) and the second latching element (22) miteinender a blocking of the relative movement of the first latching element (21) relative to the second latching element (22) against the bending direction (X) effect, and that in subsequent change in temperature in the direction of the starting temperature and the resulting Resetting the temperature bending element (1), as well as the locking mechanism 12/22 connected thereto 12 (2), the second locking element (22), the indicator element (3), preferably irreversibly, transferred from the initial state to the second state. [3] 3. Temperature monitoring unit according to claim 1 or 2, characterized in that the indicator element (3) is an electrically conductive rod, wherein the indicator element (3) consists in particular of graphite and / or in particular at its ends with an electrical contact (4a, 4b ) is electrically connected. [4] 4. Temperature monitoring unit according to claim 1 or 2, characterized in that the indicator element (3) is designed as a glass fiber rod and the second locking element (22) on its side facing the glass fiber rod an element for breaking or cutting through the indicator element (3). [5] 5. Temperature monitoring unit according to claim 3, characterized in that the second latching element (22), upon return of the temperature bending element (1), the rod (3) subjected to bending and thereby the electrical connection between the two contacts (4a) and (4b) interrupts and in particular breaks the rod (3). [6] 6. Temperature monitoring unit according to one of claims 3 or 5, characterized in that the indicator element (3) via the contacts (4a, 4b) is conductively connected to electrical components and / or measuring devices, in particular a conductivity meter (9). [7] 7. Temperature monitoring unit according to one of the preceding claims, characterized in that the first latching element (21) of the latching mechanism (2) when cooled in Abkühlungsbiegerichtung (X) of the temperature bending element (1) relative to a second latching element (22) of the latching mechanism (2) , so far shifts that the first latching element (21) and the second latching element (22) miteinender a blocking of the relative movement of the first latching element (21) relative to the second latching element (22) against the Abkühlbiegerichtung (X) effect and that in subsequent heating and the resulting resetting of the temperature bending element (1) and of the latching mechanism (2) connected thereto, the second latching element (22) transfers the indicator element (3) from the initial state to the second state, in particular the second latching element (22) the indicator element (3) bending stressed and the indicator element (3) preferably breaks. 13/22 13 [8] 8. Temperature monitoring unit according to one of the preceding claims, characterized by an RFID / NFC transponder, which is electrically conductively connected to the contacts (4a, 4b) and, upon request, the presence of the interruption of the electrically conductive connection between the contacts (4a, 4b) checks and emits a related electromagnetic signal. [9] 9. Temperature monitoring unit according to one of the preceding claims, characterized by a viewing window through which the indicator element (3) is visible from the outside wherein the second locking element (22), upon return of the temperature bending element (1), on the indicator element (3) one, through the viewing window noticeable change of the indicator element (3) generated. [10] 10. Temperature monitoring unit according to one of the preceding claims, characterized by a viewing window through which the indicator element (3) is visible, wherein the indicator element (3) is formed as a fluid-containing container (1), and that the second latching element (22), at Resetting the temperature bending element (1) opens the container, so that the substance escapes and is visible in the viewing window, wherein the substance generates a color reaction, in particular with a substance applied to a viewing window. [11] 11. Temperature monitoring unit according to one of the preceding claims, characterized in that the temperature bending element (1) at its the first latching element (21) distal end with the indicator element (3) is connected, wherein the indicator element (3) in the bending plane of the temperature bending element (1 ) and opposite to the temperature bending element (1) against the bending direction (X) is arranged offset. [12] 12. Temperature monitoring unit according to one of the preceding claims, characterized in that the locking element (21) far end of the temperature bending element (1) and the indicator element (3) to a holder (7) or to each other with a holder (7) are rigidly fixed. [13] 13. Temperature monitoring unit according to one of the preceding claims, characterized in that the first latching element (21) is designed as a latching sleeve with internal in against bending direction (X) verkippbarem latching hook (5), wherein the first latching element (21) has a recess (23) through which the second latching element (22) protrudes, wherein the second latching element (22) has at least one tooth 14/22 14 (6), in particular a plurality of teeth (6) arranged one behind the other, and is preferably designed as a toothed rack. [14] 14. Temperature monitoring unit according to one of the preceding claims, characterized in that the temperature bending element (1) is designed as a bimetal, namely as a metal element with two layers of different metals, which are connected cohesively or positively. [15] 15. Temperature monitoring unit according to one of the preceding claims, characterized in that the arrangement of the latching elements (21, 22) relative to the movement of the first latching element (21) relative to the second latching element (22) against the Abkühlbiegerichtung (X) at a cooling of the temperature bending element (1 ) is blocked in a temperature range of -200 ° C to -50 ° C. [16] 16. Temperature monitoring unit according to one of the preceding claims, characterized in that after previous cooling when exceeding a threshold temperature, in particular less than or equal to -100 ° C, the consequent regression of the bending of the temperature bending element (1) and the associated latching mechanism (2) in that the second latching element (22) irreversibly converts the indicator element (3) from the initial state into the second state. [17] 17. Use of a temperature monitoring unit (10) according to one of the preceding claims, wherein the temperature monitoring unit (10) is fastened in particular to the wall of the vial. Vienna, 30th November 2012 15/22
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同族专利:
公开号 | 公开日 EP2926101B1|2018-01-31| WO2014082112A2|2014-06-05| WO2014082112A3|2014-09-04| EP2926101A2|2015-10-07| AT513653B1|2018-07-15|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 DE19721964A1|1997-05-26|1998-12-03|Bartels Mikrotechnik Gmbh|Temp cycle counter e.g for medical instruments| US20030188677A1|1999-04-28|2003-10-09|Akers Jeffrey W.|Shape memory thermal exposure monitor| SU1696901A1|1989-04-11|1991-12-07|Научно-производственное объединение "Ротор"|Robust thermometer|RU188544U1|2017-10-18|2019-04-16|федеральное государственное бюджетное образовательное учреждение высшего образования "Ижевский государственный технический университет имени М.Т. Калашникова"|INSTALLATION FOR EXPERIMENTAL STUDY OF SPRAYER COOLING OF SPRINGS| RU207371U1|2021-07-20|2021-10-25|Владимир Семенович Мельников|ELECTRIC CONNECTOR HEATING SENSOR|
法律状态:
2020-08-15| MM01| Lapse because of not paying annual fees|Effective date: 20191130 |
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申请号 | 申请日 | 专利标题 ATA50551/2012A|AT513653B1|2012-11-30|2012-11-30|Temperature Monitoring Unit|ATA50551/2012A| AT513653B1|2012-11-30|2012-11-30|Temperature Monitoring Unit| EP13811761.9A| EP2926101B1|2012-11-30|2013-12-02|Temperature monitoring unit| PCT/AT2013/050231| WO2014082112A2|2012-11-30|2013-12-02|Temperature monitoring unit| 相关专利
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